The DVD volumes of Zero no Tsukaima: Princesses no Rondo contain Picture Drama episodes with captivating titles. Volume 1 features 'Maid's Afternoon: Whip of Love,' volume 2 showcases 'Maid's Afternoon: Afternoon for Two,' volume 3 presents 'Maid's Afternoon: The Last Night,' volume 4 offers 'Countess Butterfly's Graceful Day Prologue,' volume 5 unfolds 'Countess Butterfly's Graceful Day Chapter 1,' volume 6 delves into 'Countess Butterfly's Graceful Day Chapter 2,' and volume 7 concludes with 'Countess Butterfly's Graceful Day The Last Chapter.'